Poly[(μ3-3,5-diisopropyl-4H-1,2,4-triazolato-κ3 N:N′:N′′)silver(I)]
نویسندگان
چکیده
In the polymeric title compound, [Ag(C8H14N3)] n , the Ag(I) cation is coordinated by three N atoms from three 3,5-diisopropyl-1,2,4-triazolate anions in a T-shaped geometry. The Ag(I) cation deviates from the coordination plane by 0.014 (1) Å and the N-Ag-N bond angles are 96.85 (11), 97.72 (10) and 165.39 (12)°. The triazolate anion bridges three Ag(I) cations, forming a three-dimensional polymeric network.
منابع مشابه
Experimental and theoretical study of the coordination of 1,2,4-triazolato, tetrazolato, and pentazolato ligands to the [K(18-crown-6)]+ fragment.
Treatment of 3,5-diisopropyltriazole, 3,5-diphenyltriazole, 3,5-di-3-pyridyltriazole, phenyltetrazole, pyrrolidinyltetrazole, or tert-butyltetrazole with equimolar quantities of potassium hydride and 18-crown-6 in tetrahydrofuran at ambient temperature led to slow hydrogen evolution and formation of (3,5-diisopropyl-1,2,4-triazolato)(18-crown-6)potassium (88%), (3,5-diphenyl-1,2,4-triazolato)(t...
متن کاملPoly[(3,5-dinitrobenzoato)-μ3-triazolato-cobalt(II)]
The title compound, [Co(C(2)H(2)N(3))(C(7)H(3)N(2)O(6))](n), was obtained by the reaction of CoCl(2), triazole and 3,5-dinitro-benzoic acid in a 1:1:1 ratio. The Co centre is in a distorted tetrahedral coordination by three N atoms of three different triazole ligands and one O atom of the 3,5-dinitrobenzoate anion.
متن کاملPoly[tetraaquabis(μ3-benzene-1,3-dicarboxylato-κ3 O:O′:O′′)bis(μ2-benzene-1,3-dicarboxylato-κ3 O,O′:O′′)[μ2-1,4-bis(1,2,4-triazol-1-yl)butane-κ2 N:N′]tetrazinc(II)]
In the crystal structure of the title compound, [Zn(4)(C(8)H(4)O(4))(4)(C(8)H(12)N(6))(H(2)O)(4)](n), one Zn(II) atom is four-coordinated in a slightly distorted tetra-hedral geometry by two O atoms from benzene-1,3-dicarboxyl-ate (BDC) ligands, one N atom from a 1,4-bis-(1,2,4-triazol-1-yl)butane (BTB) ligand and one water mol-ecule, while a second Zn(II) atom is five-coordinated in a distorte...
متن کاملPoly[[μ3-N,N′-bis(3-pyridylmethyl)thiourea-κ3 N:N′:S]iodidocopper(I)]
In the title coordination polymer, [CuI(C(13)H(14)N(4)S)](n), the Cu(I) atom is coordinated by two N atoms from two N,N'-bis-(3-pyridylmeth-yl)thio-urea ligands, as well as by the S atom of a third ligand and an I atom to confer a distorted tetra-hedral coordination at the metal centre. The coordination bonds give rise to a layer structure parallel to (010).
متن کاملEarly transition metal complexes containing 1,2,4-triazolato and tetrazolato ligands: synthesis, structure, and molecular orbital studies.
Several early transition metal complexes bearing 1,2,4-triazolato and tetrazolato ligands have been prepared by reaction of the pyrazolato complexes Ti(tBu(2)pz)(4-x)Cl(x) (tBu(2)pz = 3,5-di-tert-butylpyrazolato; x = 1, 2) and M(tBu(2)pz)(5-x)Cl(x) (M = Nb, Ta: x = 2, 3) with the sodium or potassium salts derived from 1,2,4-triazoles and tetrazoles. The X-ray structure analysis of Ti(tBu(2)pz)(...
متن کامل